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Figure 4: Siloxan polymerization on chitosan microspheres by using immobilized protein templates.

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Reprinted with permission from [61]. Copyright Elsevier. Reprinted w However, in our classification we consider within this group all approaches in which a shell is formed on the surface of a particle.

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Magnetic cobalt silicate could be also generated by introducing a cobalt salt during the process. Biopolymer-stabilized simple geometries droplets, micelles, and vesicles : Surface-active polymers can assemble in solution and in heterophase systems to form defined geometries, most typically spherical, such as micelles, vesicles, or even stabilized droplets.

In a very recent work, Taheri et al. The capsules are prepared in an inverse water-in-oil miniemulsion and the surfactant polyglycerine-polyricinoleate PGPR is used to stabilize the system. We have decided to include it within this subsection mainly due to the spherical geometry and the presence of a heterophase system, but probably the example could have been included as well in the next subsection, as the silver precipitation takes place within the polymer scaffold.

Reprinted with permission from [63]. Copyright The Royal Society of Chemistry. As an extension of the metallization examples presented in Section B1, structures formed by DNA or proteins can also be used for templating. Rings resulting from the assembly of a bolaamphiphilic peptide molecule were reported as templates for the growth of conductive indium tin oxide ITO nanoparticles [67].

Reprinted with permission from [66]. In addition to the common applications in food and biotechnology, chitosan can also be used as a support for catalysts. Chitosan—silica [69] and chitosan—titania [70] catalysts were prepared by applying conventional sol—gel methods. The preparation of sol—gel silicates have been reported by several research groups [71,72].

Nevertheless, the use of chitosan is not limited to silicates and titanates. El Kadib et al. Similarly, Ganesan and Gedanken [74] had prepared tungsten VI oxide nanoparticles through the encapsulation of ammonium metatungstate on chitosan and the subsequent calcination. These particles showed a higher catalytic activity than bulk tungsten trioxide. Other materials, such as cobalt-Prussian blue nanoparticles [75] , Zn—Al layered double hydroxide [76] , hydroxyapatite [77] , and calcium carbonate [78] , were also prepared within, or in the presence of, chitosan gels.

2017, Vol.90, No.5

Lee et al. Alginate is another of the gelling biopolymers used as a scaffold. The same research group also studied the in situ growth of gold colloids with alginate films [81,82].


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Gel frameworks have been shown to be able to control the size distribution of particles. Gold and AuNi alloy gelatin nanocomposites were developed by Brayner et al. A gelatin network incorporating metallic nanoparticles was obtained after reduction of gold salts. Like other gel biopolymer templates, gelatin has also been used in silicate sol—gel processes [72,85,86]. Ethirajan et al. Reprinted with permission from [87].

Inorganic syntheses. Volume 35 — University of Illinois at Urbana-Champaign

Also for catalytic applications, nanoparticles of silver, gold, and platinum were synthesized by using a cellulose aerogel [89]. Cellulose has been further used for silicates. Zhang et al. The aerogel is formed by drying with supercritical CO 2 and subsequent calcination. Figure 8: Schematic representation of aerogel preparation. A nanoporous cellulose gel is impregnated with the silica precursor TEOS a.

Inorganic syntheses. volume 35 /

Afterwards, the silica formation takes place by sol—gel process hydrolysis and condensation , yielding a cellulose—silica composite gel b. Drying with supercritical CO 2 gives a composite aerogel c. Macroscopic views of the prepared samples are shown in panels e—h.


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  6. Reprinted with permission from [90]. A nanoporous cellulose gel is impregnated with the Scaffold templating can also be achieved with starch and even with peptides. Thakore et al. Hexagonal silica platelets were prepared through a polypeptide-templated synthesis by using the interactions of a polypeptide of L-lysine with silicate [35].

    On one hand, biopolymers may assemble forming structures that serve as confining spaces or scaffolds in which the formation of the inorganic component takes place. On the other hand, the presence of functional groups such as carboxylic, amino or phosphate groups can provide a high ability to bind metal ions or to interact with growing crystal faces, influencing nucleation and growth.

    Hydrogels, such as those formed with chitosan or gelatin, are very commonly used as polymer matrices for the synthesis of porous structures. Although in general the inorganic material is formed in situ i. In most cases, biopolymers have been either used in bulk solutions or applied to surfaces, so that the resulting material is a continuous hybrid structure. Hydrogel approaches can also be confined to the spaces of particles. Clearly, synthetic polymers are often a more economic and versatile alternative, but biopolymers can be especially interesting in those applications in which biocompatibility or biodegradability are an issue, such as biomedical applications.

    In addition, biopolymers may be also good model systems. In this sense, for instance, peptides or nucleic acids of defined length and structure can be very convenient models for studying polyelectrolyte systems. Furthermore, the high ability of biopolymers to form complex hierarchical structures is a major feature to be explored in the upcoming years.

    A better understanding of the interface between the biopolymeric component and the growing inorganic matter will continue to be the crucial issue in the design of novel and more sophisticated materials. Claudia Steinem and Joachim Bill. Aleksey A.

    Egorov, Alexander Yu. Fedotov, Anton V. Mironov, Vladimir S. Komlev, Vladimir K. Popov and Yury V.

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    Siles, Feng Zhu and Oliver G. Twitter: BeilsteinInst. Beilstein J. Ignoreeri ja kuva leht. Inorganic Syntheses Inc. Teised raamatud teemal : Chemistry - Hetkel poes: 14 nimetust.

    Suurem pilt. Tutvustus Sisukord Autori biograafia Arvustused Goodreads'ist Chemists from around the world describe procedures that illustrate the scope of modern inorganic and organometallic synthesis. Following the tradition of the series, they emphasize useful compounds; following Rauchfuss' U. Drying with supercritical CO 2 gives a composite aerogel c. Macroscopic views of the prepared samples are shown in panels e—h. Reprinted with permission from [90].

    A nanoporous cellulose gel is impregnated with the Scaffold templating can also be achieved with starch and even with peptides. Thakore et al. Hexagonal silica platelets were prepared through a polypeptide-templated synthesis by using the interactions of a polypeptide of L-lysine with silicate [35].